Formatting can be set for merge fields whose data type is Currency or Number. Available in Ver.2.0 or later.
Merge Field Format
{!Object API Name.Field API Name, Format;Minus Format, Rounding Mode}
e.g. {!Case.TestCurrency__c, #,##0;(#,##0)}
Value: -1234
Result: (1,234)
*In Excel, merge fields cannot be formatted. Set the format from "Format Cells".
Instruction manual
Formatting of Currency and Number Fields